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上海海事大学蓄冷技术研究所
纸质出版日期:2017,
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陈裕丰, 章学来, 丁锦宏, 等. 癸酸/辛酸-纳米复合相变材料的热物性实验研究[J]. 制冷学报, 2017,38(5).
CHEN YUFENG, ZHANG XUELAI, DING JINHONG, et al. Experimental Research on Thermophysical Properties of Capric/Caprylic Acid Nanocomposite Phase Change Material. [J]. Journal of refrigeration, 2017, 38(5).
陈裕丰, 章学来, 丁锦宏, 等. 癸酸/辛酸-纳米复合相变材料的热物性实验研究[J]. 制冷学报, 2017,38(5). DOI: 10.3969/j.issn.0253-4339.2017.05.041.
CHEN YUFENG, ZHANG XUELAI, DING JINHONG, et al. Experimental Research on Thermophysical Properties of Capric/Caprylic Acid Nanocomposite Phase Change Material. [J]. Journal of refrigeration, 2017, 38(5). DOI: 10.3969/j.issn.0253-4339.2017.05.041.
针对脂肪酸有机物癸酸/辛酸(质量比30:70)复合相变材料存在导热系数低的缺点,本文分别按不同比例添加10~30 nm的纳米铜粉、纳米氧化铝和纳米氧化铁制备出癸酸/辛酸纳米复合相变材料。实验结果表明:添加了质量分数为0.1%~0.4%的纳米材料后,复合相变材料具有良好的热稳定性,未出现沉淀现象。热物性参数方面,导热系数与原基液相比有大幅度提高,依次提高5.1%~6.5%、4.0%~12.4%、6.7%~17.5%,相变温度点波动范围小(±0.39 ℃),相变潜热变化不大,提高幅度为2.2%~5.5%,因此选择适当适量的纳米材料可改善了原相变材料的热物性,具有一定的研究意义。
To increase the thermal conductivity of organic fatty phase change material (PCM)
different mass fractions of nanoparticles with high thermal conductivity
including 10?30-nm copper powder
alumina
and iron oxide
were individually added to composite PCMs of capric/caprylic acid (with a 30:70 mass ratio). The experimental results show that the composite PCMs exhibit good thermal stability and zero precipitation after the addition of nanoparticles at a mass fraction of 0.1?0.4%. Compared with the original material
the thermal conductivity is greatly improved by 5.1%-6.5%
4.0%-12.4%
6.7%-17.5%
for the copper powder
alumina
and iron oxide
respectively. The fluctuation range of the phase change temperature is small (±0.39℃). The phase change latent heat varies little and the increase range is 2.2%-5.5%. Therefore
the selection of appropriate amounts of nanomaterials can improve the thermal properties of the original PCMs
which may have wide potential application.
复合相变材料热物性纳米材料
composite phase change materialsthermal propertiesnanomaterials
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