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电卡制冷技术:器件发展现状与高熵铁电材料前瞻
杨世豪1, 钱小石2
0
(1.上海交通大学机械与动力工程学院;2.上海交通大学前瞻交叉研究中心)
摘要:
电卡制冷技术是一种基于电场调控的固态制冷技术,该技术利用电卡材料在电场作用下产生的温度变化来实现制冷效果。这种技术因其无直接碳排放、高效率等优点,在全球变暖和碳减排目标的背景下,受到了广泛关注。自2006年巨电卡效应的发现以来,电卡制冷技术经历了快速发展,尤其是在电卡材料和器件的改进上取得了显著进展。本文从电卡制冷器件研究、电卡聚合物纳米复合材料和电卡材料高熵优化方面展开分析与讨论。首先介绍电卡效应的基本原理和当前主动回热式电卡制冷器件的研究进展;其次,总结电卡聚合物纳米复合材料的研究进展,以及高熵优化策略和界面极化增强策略;最后,展望电卡制冷技术在工质和系统领域的未来研究方向。
关键词:  电卡制冷,复合材料,柔性制冷器件,热力学循环,零碳制冷与热泵
DOI:
投稿时间:2024-01-28  修订日期:2024-03-11   录用日期:2024-03-28
基金项目:国家自然科学基金项目(面上项目,重点项目,重大项目),国家重点基础研究发展计划(973计划)
Electrocaloric Cooling Technology: Current Device Developments and Prospects of High-Entropy Ferroelectric Materials
Abstract:
Electrocaloric refrigeration technology is a solid-state cooling technique based on the manipulation of electric fields. This technology exploits the temperature variations induced in electrocaloric materials under the influence of an electric field to achieve refrigeration effects. Due to its advantages, such as zero direct carbon emissions and high efficiency, it has garnered widespread attention, particularly in the context of global warming and carbon reduction objectives. Since the discovery of the giant electrocaloric effect in 2006, electrocaloric refrigeration technology has undergone rapid development, notably in the improvement of electrocaloric materials and devices. This article provides an analysis and discussion focused on electrocaloric refrigeration device research, electrocaloric polymer nanocomposite materials, and high-entropy optimization of electrocaloric materials. It commences by introducing the fundamental principles of the electrocaloric effect and current advancements in active regenerative electrocaloric refrigeration devices. Subsequently, it summarizes progress in electrocaloric polymer nanocomposite materials, along with strategies for high-entropy optimization and interface polarization enhancement. Finally, it offers insights into future research directions for electrocaloric refrigeration technology within the fields of working substances and systems.
Key words:  Electrocaloric  cooling technology, composite  materials, flexible  refrigeration devices, thermodynamic  cycles, zero-carbon  refrigeration, and  heat pumps

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