二元阻燃剂对HFO-1243zf可燃性抑制效果研究

吴曦; 区祖迪; 胡光航; 徐士鸣; 朱晓静

doi:10.3969/j.issn.0253-4339.2023.03.041

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二元阻燃剂对HFO-1243zf可燃性抑制效果研究

更新时间：2024-07-18

- 二元阻燃剂对HFO-1243zf可燃性抑制效果研究
- Flame Suppression Effects of Binary Extinguishants on the Flammability of HFO-1243zf
- 制冷学报 2023年44卷第3期
- 作者机构：
  
  大连理工大学能源与动力学院海洋能源利用与节能教育部重点实验室
- 作者简介：
- 基金信息：
  
  国家自然科学基金 (52076026) ，中央高校基本科研业务费项目(No.DUT22JC25)项目资助。
- DOI：10.3969/j.issn.0253-4339.2023.03.041
  中图分类号：
- 纸质出版日期：2023，
- 稿件说明：
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吴曦, 区祖迪, 胡光航, 等. 二元阻燃剂对HFO-1243zf可燃性抑制效果研究[J]. 制冷学报, 2023,44(3).

WU XI, OU ZUDI, HU GUANGHANG, et al. Flame Suppression Effects of Binary Extinguishants on the Flammability of HFO-1243zf. [J]. Journal of refrigeration, 2023, 44(3).
吴曦, 区祖迪, 胡光航, 等. 二元阻燃剂对HFO-1243zf可燃性抑制效果研究[J]. 制冷学报, 2023,44(3). DOI： 10.3969/j.issn.0253-4339.2023.03.041.

WU XI, OU ZUDI, HU GUANGHANG, et al. Flame Suppression Effects of Binary Extinguishants on the Flammability of HFO-1243zf. [J]. Journal of refrigeration, 2023, 44(3). DOI： 10.3969/j.issn.0253-4339.2023.03.041.

摘要

HFO-1243zf（R1243zf）是一种具有良好发展潜力的新一代低环境影响性制冷工质。R1243zf的安全性分类为A2，其可燃问题不容忽视。参考ASHRAE 34-2019标准方法，本文以12 L球形玻璃烧瓶为反应容器，实验测得了三种混合制冷剂R1243zf/R134a/R227ea、R1243zf/R125/R227ea和R1243zf/R125/R134a的临界可燃极限值，体积分数分别为10.82%~11.12%、10.49%~10.80%、10.89%~11.11%。进一步基于混合制冷剂可燃性估算理论得到上述混合物的临界抑爆浓度和临界可燃极限值，与实测结果相比，相对平均偏差分别为3.45%和1.68%。最后从化学抑制机理等角度对阻燃效果发生变化的原因进行了分析。

Abstract

HFO-1243zf (R1243zf) is a refrigerant with a low global warming effect and high development potential. The safety classification of R1243zf is A2; therefore

its flammability cannot be ignored. The critical flammability limits of R1243zf/R134a/R227ea

R1243zf/R125/R227ea

and R1243zf/R125/R134a were 10.82%–11.12%

10.49%–10.80%

and 10.89%–11.11% (by volume percentage)

respectively

which were determined using a 12 L glass flask reaction vessel

according to an experimental method described in ASHRAE 34-2019. Furthermore

both the critical suppression concentrations and critical flammability limits were calculated using a related estimation method for flammable refrigerant blends. Compared with the test results

the relative mean deviations were 3.45% and 1.68%

respectively. Finally

reasons for deviations in the retardant effect were analyzed based on the chemical inhibition mechanism.

关键词

制冷剂氢氟烯烃可燃性可燃极限333-三氟丙烯

Keywords

refrigeranthydrofluoroolefinflammabilityflammability limits333-trifluoropropylene

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