批量制备La-Fe-Si系磁热材料的磁热性能和制冷性能研究

郭亚茹; 黄焦宏; 金培育; 刘翠兰; 程娟; 张英德; 李兆杰; 戴默涵; 张建平; 高磊; 王鹏宇; 裴昊

doi:10.12465/j.issn.0253-4339.2025.02.090

您当前的位置：

首页 >

文章列表页 >

批量制备La-Fe-Si系磁热材料的磁热性能和制冷性能研究

更新时间：2025-04-15

- 批量制备La-Fe-Si系磁热材料的磁热性能和制冷性能研究
- Study of Magnetocaloric Properties and Refrigeration Performance for Batch Prepared La-Fe-Si Based Magnetocaloric Materials
- 制冷学报 2025年46卷第2期页码：90-97
- 作者机构：
  
  包头稀土研究院　白云鄂博稀土资源研究与综合利用全国重点实验室　包头　 014030
- 作者简介：
  
  黄焦宏，男，博士，教授级高工，包头稀土研究院，白云鄂博稀土资源研究与综合利用全国重点实验室，13604720121，E-mail：jiaohongh@163.com。研究方向：室温磁制冷材料的开发及应用，室温磁制冷机的设计与研制，永磁磁场的设计和装配。
- 基金信息：
  
  国家自然科学基金(52171187)
- DOI：10.12465/j.issn.0253-4339.2025.02.090
  中图分类号： TB61⁺1;TB61⁺2;O482.6
- 收稿日期：2023-10-25，
  
  修回日期：2024-01-09，
  
  录用日期：2024-01-31，
  
  纸质出版日期：2025-04-16
- 稿件说明：
移动端阅览
郭亚茹, 黄焦宏, 金培育, 等. 批量制备La-Fe-Si系磁热材料的磁热性能和制冷性能研究[J]. 制冷学报, 2025,46(2):90-97.

Guo Yaru, Huang Jiaohong, Jin Peiyu, et al. Study of Magnetocaloric Properties and Refrigeration Performance for Batch Prepared La-Fe-Si Based Magnetocaloric Materials[J]. Journal of refrigeration, 2025, 46(2): 90-97.
郭亚茹, 黄焦宏, 金培育, 等. 批量制备La-Fe-Si系磁热材料的磁热性能和制冷性能研究[J]. 制冷学报, 2025,46(2):90-97. DOI： 10.12465/j.issn.0253-4339.2025.02.090.

Guo Yaru, Huang Jiaohong, Jin Peiyu, et al. Study of Magnetocaloric Properties and Refrigeration Performance for Batch Prepared La-Fe-Si Based Magnetocaloric Materials[J]. Journal of refrigeration, 2025, 46(2): 90-97. DOI： 10.12465/j.issn.0253-4339.2025.02.090.

摘要

使用中频熔炼炉批量制备公斤级（La，Ce）（Fe，Mn，Si）

磁热材料，对合金的磁热性能和制冷性能进行了研究。结果表明：合金的居里温度随Mn含量的增加而降低，分别为292.9、287.8和283.9 K。在2 T外加磁场下，合金最大等温磁熵变达到12.0 J/（kg·K），半峰宽最大为11 K，3种合金的相对制冷能力分别为110.2、132.0和110.0 J/kg。使用课题组自制的磁热效应测量仪，得到变化磁场为1.5 T时，3种合金的最大绝热温变分别为3.48、3.14和2.96 K。将3种合金分层装入主动式磁回热器中，在课题组自制的磁制冷样机上测试制冷性能，当设定环境温度为295 K，可实现16.9 K的制冷温跨。

Abstract

This study investigates the magnetocaloric properties and refrigeration performance of batch-prepared (La

Ce)(Fe

Si)

alloys. After heat treatment and hydrogenation

the Curie temperatures of M1

and M3 were 292.9 K

287.8 K

and 283.9 K

respectively

decreasing with higher Mn content. Arrott plots indicated an itinerant-electron metamagnetic transition. M2 exhibited the highest isothermal magnetic entropy change of 12.0 J/(kg·K) under a 2 T magnetic field

with a full width at half maximum of 11 K. Relative cooling capacities (RCP) were 110.2 J/kg

132.0 J/kg

and 110.0 J/kg for M1

and M3

respectively. Adiabatic temperature changes measured under a 1.5 T magnetic field were 3.48 K

3.14 K

and 2.96 K for M1

and M3

respectively. A maximum refrige

ration temperature span of 16.9 K was achieved by cascading the alloys at an ambient temperature of 295 K.

关键词

Keywords

references

LU Xiang , ZENG Shuang , ZHANG Yifei , et al . Effect of annealing on microstructure and magnetocaloric properties of plastically deformed La 0.7 Ce 0.3 Fe 13.68 Mn 0.2 Si 1.4 alloys [J ] . Journal of Materials Research and Technology , 2022 , 18 : 2282 - 2291 .

WANG Siyang , GAVALDA-DIAZ O , LUO Ting , et al . The effect of hydrogen on the multiscale mechanical behaviour of a La(Fe, Mn, Si) 13 -based magnetocaloric material [J ] . Journal of Alloys and Compounds , 2022 , 906 : 164274 .

WANG Siyang , BURDETT P , LOVELL E , et al . Fracture properties of La(Fe, Mn, Si) 13 magnetocaloric materials [J ] . Materials Letters , 2023 , 338 : 134034 .

CHUNG K C , SHINDE K P , KANG K H , et al . Magnetocaloric properties of a wire composite of La (Fe, Mn, Si) 13 -H alloy powders in a Gd cylindrical tube [J ] . Journal of Alloys and Compounds , 2023 , 947 : 169551 .

IMAIZUMI K , FUJITA A , SUZUKI A , et al . Improvement of magnetocaloric effect in La(Fe x Si 1 - x ) 13 by dealing with inhibitory microstructures at high Fe concentration [J ] . Acta Materialia , 2022 , 227 : 117726 .

DAN′KOV S Y , TISHIN A M , PECHARSKY V K , et al . Magnetic phase transitions and the magnetothermal properties of gadolinium [J ] . Physical Review B , 1998 , 57 ( 6 ): 3478 - 3490 .

TASKAEV S , KHOVAYLO V , KARPENKOV D , et al . Plastically deformed Gd-X (X=Y, In, Zr, Ga, B) solid solutions for magnetocaloric regenerator of parallel plate geometry [J ] . Journal of Alloys and Compounds , 2018 , 754 : 207 - 214 .

NIKITIN S A , SMIRNOV A V , OVCHENKOVA I A , et al . The influ ence of titanium substitution on the magnetic, magnetocaloric and magnetoelastic properties of Gd 5 Si 2 Ge 2 [J ] . Journal of Applied Physics , 2018 , 124 ( 8 ): 083902 .

TEGUS O , BRÜCK E , BUSCHOW K H J , et al . Transition-metal-based magnetic refrigerants for room-temperature applications [J ] . Nature , 2002 , 415 ( 6868 ): 150 - 152 .

QIAN Mingfang , ZHANG Xuexi , WEI Longsha , et al . Tunable magnetocaloric effect in Ni-Mn-Ga microwires [J ] . Scientific Reports , 2018 , 8 : 16574 .

MIAO Liya , LU Xiang , ZHANG Yifei , et al . Unique layered microstructure and magnetocaloric effect in hot-rolled La-Fe-Co-Si plates [J ] . Journal of Magnetism and Magnetic Materials , 2022 , 561 : 169711 .

SUN Naikun , ZHAO Xinguo , SONG Yingwei , et al . Electroless plating Ni-P coatings on La(Fe, Si) 13 hydride bulks for room-temperature magnetic-refrigeration application [J ] . Journal of Magnetism and Magnetic Materials , 2021 , 525 : 167685 .

XIAN Liang , YU Jian , LIN Weixiao , et al . Preparation and magnetocaloric performance of La(Fe, Co, Si) 13 alloys with wide transition temperature range [J ] . Intermetallics , 2023 , 154 : 107827 .

KRAUTZ M , SKOKOV K , GOTTSCHALL T , et al . Systematic investigation of Mn substituted La(Fe, Si) 13 alloys and their hydrides for room-temperature magnetocaloric application [J ] . Journal of Alloys and Compounds , 2014 , 598 : 27 - 32 .

BASSO V , KÜPFERLING M , CURCIO C , et al . Specific heat and entropy change at the first order phase transition of La(Fe-Mn-Si) 13 -H compounds [J ] . Journal of Applied Physics , 2015 , 118 ( 5 ): 053907 .

FUJIEDA S , FUJITA A , FUKAMICHI K , et al . Giant isotropic magnetostriction of itinerant-electron metamagnetic La(Fe 0.88 Si 0.12 ) 13 H y compound s [J ] . Applied Physics Letters , 2001 , 79 ( 5 ): 653 - 655 .

WANG Fang , CHEN Yuanfu , WANG Guangjun , et al . The effect of Mn substitution in LaFe 11.7 Si 1.3 compound on the magnetic properties and magnetic entropy changes [J ] . Journal of Physics D Applied Physics , 2003 , 36 ( 1 ): 1 - 3 .

LIONTE S , BARCZA A , RISSER M , et al . LaFeSi-based magnetocaloric material analysis: cyclic endurance and thermal performance results [J ] . International Journal of Refrigeration , 2021 , 124 : 43 - 51 .

YUAN Lifen , QIAN Suxin , YU Jianlin . Numerical study on the multi-layered magnetocaloric regenerators [J ] . Applied Thermal Engineering , 2022 , 204 : 118001 .

张文佳 , 黄焦宏 , 慕利娟 , 等 . 吸放氢对La 0.8 Ce 0.2 Fe 11.44 Si 1.56 合金磁热性能的影响 [J ] . 稀有金属 , 2015 , 39 ( 3 ): 221 - 226 .

( ZHANG Wenjia , HUANG Jiaohong , MU Lijuan , et al . Magnetocaloric properties of La 0.8 Ce 0.2 Fe 11.44 Si 1.56 alloy by hydrogen absorption and desorption [J ] . Chinese Journal of Rare Metals , 2015 , 39 ( 3 ): 221 - 226 .)

高磊 , 黄焦宏 , 张英德 , 等 . 室温磁工质与磁制冷机的研究和开发 [J ] . 制冷学报 , 2022 , 43 ( 4 ): 77 - 87 .

( GAO Lei , HUANG Jiaohong , ZHANG Yingde , et al . Research and development of room-temperature magnetic refrigerant and magnetic refrigerator [J ] . Journal of Refrigeration , 2022 , 43 ( 4 ): 77 - 87 .)

BARCZA A , KATTER M , ZELLMANN V , et al . Stability and magnetocaloric properties of sintered La(Fe, Mn, Si) 13 H z alloys [J ] . IEEE Transactions on Magnetics , 2011 , 47 ( 10 ): 3391 - 3394 .

SUN Naikun , ZHANG Yang , ZHAO Xinguo , et al . Microstructure, mechanical and magnetocaloric properties of bulk La 0.9 Ce 0.1 Fe 11.7- x Mn x Si 1.3 hydrides prepared by high-hydrogen-pressure sintering [J ] . Journal of Magnetism and Magnetic Materials , 2020 , 495 : 165889 .

LI Yueqiao , HU Fengxia , SHEN Feiran , et al . Excellent mechanical properties and age stability of hydrogenated La 0.8 Ce 0.2 Fe 12.5 Mn 0.2 Si 1.3 H δ plates with extra Fe [J ] . Journal of Alloys and Compounds , 2018 , 743 : 221 - 226 .

GAO Lei , WANG Pengyu , GUO Yaru , et al . Performance study of a double-regenerator room temperature magnetic refrigerator with 26 ℃ temperature span [J ] . International Journal of Refrigeration , 2023 , 148 : 143 - 151 .

NAVICKAITĖ K , BEZ H N , LEI Tian , et al . Experimental and numerical comparison of multi-layered La(Fe, Si, Mn) 13 H y active magnetic regenerators [J ] . International Journal of Refrigeration , 2018 , 86 : 322 - 330 .

ZHANG Yaokang , WU Jianghong , ZHANG Hangye . Performance analysis of a cascade room temperature magnetic refrigerator for improving temperature span [J ] . International Journal of Refrigeration , 2022 , 143 : 68 - 77 .

CHEN Xiang , CHEN Yungui , TANG Yongbo . The influence of different cooling processes on phase, microstructure, and magnetocaloric properties of LaFe 11.6 Si 1.4 compounds [J ] . Solid State Communications , 2014 , 186 : 56 - 63 .

LEI Tian , NIELSEN K K , ENGELBRECHT K , et al . Sensitivity study of multi-layer active magnetic regenerators using first order magnetocaloric material La(Fe, Mn, Si) 13 H y [J ] . Journal of Applied Physics , 2015 , 118 ( 1 ): 014903 .

BAHL C R H , NAVICKAIT Ė K , BEZ H N , et al . Operational test of bonded magnetocaloric plates [J ] . International Journal of Refrigeration , 2017 , 76 : 245 - 251 .

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

批量制备La-Fe-Si系磁热材料的磁热性能和制冷性能研究

带喷射器的低温跨临界CO₂两级压缩制冷系统性能

急速冷冻箱制冷性能实验研究

CO2复叠制冷系统与载冷剂制冷系统适用范围研究

孔结构分布对活性炭-甲醇工质对吸附制冷特性的影响