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华北电力大学能源动力与机械工程学院,北京,102206
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高峰, 李元媛, 陆规. 含纳米颗粒悬浮液滴蒸发及颗粒沉积特性研究[J/OL]. 制冷学报, 2025.
Research on evaporation and deposition characteristics of suspended droplets containing nanoparticles. [J/OL]. Journal of refrigeration, 2025.
含功能性纳米颗粒液滴在固体表面上的蒸发是空调制冷、电子冷却等多个领域的关键过程。本文通过实验研究纳米流体液滴在固体表面上的蒸发和颗粒沉积过程,拍摄沉积图案并进行微观表征。结果表明,液滴始终以恒定接触半径模式蒸发,基板温度和液滴体积的变化对液滴蒸发模式和形态影响较小,接触角随时间基本呈现线性变化。表面活性剂可极大调控液滴铺展动力学行为,仅添加质量分数0.25 wt %的表面活性剂十二烷基硫酸钠(SDS)可使液滴的铺展半径从0.71 mm增加到1.12 mm,初始接触角从83°降低到54°,铺展面积增加89%。此外,SDS可以调控增加咖啡环宽度,当SDS浓度达到1%时,咖啡环宽度达到230 μm,颗粒已经较为均匀的分布在整个蒸发区域内,有效地抑制了咖啡环效应。基板温度和液滴体积显著影响液滴蒸发后的沉积图案,基板温度越高,液滴体积越大,蒸发后形成更为明显的咖啡环图案。通过引入Ma数,定量表征了温度,体积和浓度变化引导的Marangoni效应对液滴内部流动及咖啡环形成机理的影响机制。
Evaporation of functional nanoparticle-containing droplets on solid surfaces is a key process in several fields
such as air conditioning
refrigeration
and electronics cooling. In this paper
we experimentally investigate nanofluid droplets' evaporation and particle deposition process on solid surfaces
photograph the deposition patterns
and perform microscopic characterization. The results show that the droplets always evaporate in the mode of constant contact radius
the changes in substrate temperature and droplet volume have little influence on the evaporation mode and morphology of the droplets
and the contact angle changes linearly with time. The surfactant can significantly regulate the kinetic behavior of droplet spreading
and the addition of only 0.25 wt % of surfactant sodium dodecyl sulfate (SDS) increases the droplet spreading radius from 0.71 mm to 1.12 mm
the initial contact angle decreases from 83° to 54°
and the area of spreading increases by 89%. Substrate temperature and droplet volume significantly affect the deposition pattern after droplet evaporation. The higher the substrate temperature
the larger the droplet volume
and the more obvious coffee ring pattern is formed after evaporation. SDS significantly increases the coffee ring width
which reaches 230 μm when the concentration of SDS reaches 1%
and the particles have been widely distributed throughout the entire evaporation area
suggesting that the coffee ring effect has been effectively suppressed. By introducing the Ma number
the influence of the Marangoni effect guided by temperature
volume
and concentration changes on the internal flow of droplets and the mechanism of coffee ring formation is explained.
纳米流体液滴蒸发颗粒自组装咖啡环
nanofluidsdroplet evaporationParticle self-assemblyCoffee ring
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