Construction and Performance Study of a Transcritical High-Temperature Heat Pump System with Phase Change Thermal Storage

Deng Mengqing; Zhang jiankai; Chen Jianyong; Chen Ying; Luo Xianglong; Liang Yingzong; He Jiacheng

doi:10.12465/issn.0253-4339.20260112001

您当前的位置：

首页 >

文章列表页 >

Construction and Performance Study of a Transcritical High-Temperature Heat Pump System with Phase Change Thermal Storage

更新时间：2026-04-24

- Construction and Performance Study of a Transcritical High-Temperature Heat Pump System with Phase Change Thermal Storage
- Journal of Refrigeration Pages: 1-10(2026)
- 作者机构：
  
  广东工业大学材料与能源学院广州 510006
- 作者简介：
- 基金信息：
  
  the National Natural Science Foundation of China(52476003;52376003)
- DOI：10.12465/issn.0253-4339.20260112001
  CLC： TU833;TK02
- Received：12 January 2026，
  
  Revised：2026-01-27，
  
  Accepted：03 February 2026，
  
  Online First：24 April 2026，
- 稿件说明：
移动端阅览
邓孟清,张健恺,陈健勇等.储热型跨临界高温热泵系统的构建和性能研究[J].制冷学报,

Deng Mengqing Zhang jiankai Chen Jianyong Chen Ying Luo Xianglong Liang Yingzong,He Jiacheng Yang Zhi.Construction and Performance Study of a Transcritical High-Temperature Heat Pump System with Phase Change Thermal Storage[J].Journal of Refrigeration,
邓孟清,张健恺,陈健勇等.储热型跨临界高温热泵系统的构建和性能研究[J].制冷学报, DOI：10.12465/issn.0253-4339.20260112001.

Deng Mengqing Zhang jiankai Chen Jianyong Chen Ying Luo Xianglong Liang Yingzong,He Jiacheng Yang Zhi.Construction and Performance Study of a Transcritical High-Temperature Heat Pump System with Phase Change Thermal Storage[J].Journal of Refrigeration, DOI：10.12465/issn.0253-4339.20260112001.

摘要

工业余热高效回收对实现工业“双碳”目标至关重要。本文针对中低温余热所面临的利用率低、大温升需求和时间不匹配等挑战，以回收空压站连续余热以满足工业间断高温热需求，开展了基于非共沸工质和梯级相变储热的跨临界高温热泵系统的设计与性能研究。首先，通过单目标优化，筛选出综合性能最优的非共沸工质R290/cis-Butene（0.5/0.5），其COP为3.31且单位容积制热量（VHC）达到5 975.63 kJ/m

。然后，获得了储热器的结构参数，确定梯级相变材料（PCM）的优化配置为高温石蜡与低温石蜡体积比25∶35。最后，研究了系统运行性能，结果表明：梯级PCM配置（Case1）降低了充放热过程中PCM温度不均匀性，并在放热过程中能维持更高的平均出口温度，其性能最优，平均COP达2.88，且压缩机功耗最低。

Abstract

Efficient recovery of industrial waste heat is crucial for achieving the industrial "dual-carbon" goals. In this study， we addressed the challenges associated to low- and medium-temperature waste heat， such as low utilization rates， demand for high-temperature lift， and temporal mismatch. We focused on recovering continuous waste heat from an air compressor station to meet intermittent high-temperature industrial heat demand. We also researched on the design and performance of a transcritical high-temperature heat pump system based on a zeotropic mixture and cascaded phase-change thermal storage. First， via single-objective optimization， the optimal zeotropic mixture R290/cis-Butene （0.5/0.5） was selected， achieving a coefficient of performance （COP） of 3.31 and a volumetric heating capacity （VHC） of 5 975.63 kJ/m³. Subsequently， the structural parameters of the thermal storage unit were obtained， and the optimized configuration of the cascaded phase-change materials （PCMs） was determined to be a volume ratio of 25∶35 for high-temperature to low-temperature paraffin. Finally， the operational performance of the system was investigated. The results show that the cascaded PCM configuration （Case 1） reduces temperature non-uniformity within the PCM during both charging and discharging processes， maintains a higher average outlet temperature during discharge， and achieves optimal performance with an average COP of 2.88 and the lowest compressor power consumption.

关键词

Keywords

references

Gailani A ， Cooper S ， Allen S ， et al . Assessing the potential of decarbonization options for industrial sectors ［J］. Joule ， 2024 ， 8 （ 3 ）： 576 - 603 .

胡斌，姜佳彤，吴迪，等 . 工业高温热泵发展现状与展望［J］. 制冷学报， 2023 ， 44 （ 6 ）： 1 - 12 .

Hu Bin ， Jiang Jiatong ， Wu Di ， et al . Development status and prospects of industrial high-temperature heat pumps ［J］. Journal of Refrigeration ， 2023 ， 44 （ 6 ）： 1 - 12 .

Adamson K M ， Walmsley T G ， Carson J K ， et al . High-temperature and transcritical heat pump cycles and advancements： a review ［J］. Renewable and Sustainable Energy Reviews ， 2022 ， 167 ： 112798 .

Besbes K ， Zoughaib A ， Carlan F ， et al . A R-32 transcritical heat pump for high temperature industrial applications ［C］// 24th IIR International Congress of Refrigeration ， 2015 .

Vieren E ， Demeester T ， Beyne W ， et al . The thermodynamic potential of high-temperature transcritical heat pump cycles for industrial processes with large temperature glides ［J］. Applied Thermal Engineering ， 2023 ， 234 ： 121197 .

Zhao An ， Pecnik R ， Peeters J W R . Thermodynamic analysis and heat exchanger calculations of transcritical high-temperature heat pumps ［J］. Energy Conversion and Management ， 2024 ， 303 ： 118172 .

Gómez-Hernández J ， Grimes R ， Briongos J V ， et al . Carbon dioxide and acetone mixtures as refrigerants for industry heat pumps to supply temperature in the range 150–220 ℃ ［J］. Energy ， 2023 ， 269 ： 126821 .

Ganesan P ， Eikevik T M . New zeotropic CO 2 -based refrigerant mixtures for cascade high-temperature heat pump to reach heat sink temperature up to 180 ℃ ［J］. Energy Conversion and Management： X ， 2023 ， 20 ： 100407 .

Suresh C ， Awasthi A ， Kumar B ， et al . Comprehensive review on heat pump systems integrated with phase change material-based thermal energy storage for sustainable building heating ［J］. Renewable and Sustainable Energy Reviews ， 2026 ， 226 ： 116197 .

Huang Yanjie ， Chen Jianyong ， Chen Ying ， et al . Benefits of zeotropic mixture for heat pump water heater with phase change material thermal energy storage ［J］. Applied Thermal Engineering ， 2025 ， 258 ： 124652 .

杨耿，肖鑫，王云峰 . 压缩式热泵耦合相变储热的研究进展［J］. 制冷学报， 2025 ， 46 （ 1 ）： 32 - 45 .

Yang Geng ， Xiao Xin ， Wang Yunfeng . Research progress of compression heat pump coupled with heat storage of phase change materials ［J］. Journal of Refrigeration ， 2025 ， 46 （ 1 ）： 32 - 45 .

邢刚，杨涵，乔永辉，等 . 卡诺电池分类与关键要素研究进展［J/OL］. 材料导报， 1 - 28 . （ 2025-10-20 ）［ 2026-01-04 ］. https：//link.cnki.net/urlid/50.1078.TB.20251019.1651.006 https://link.cnki.net/urlid/50.1078.TB.20251019.1651.006 .

Xing Gang ， Yang Han ， Qiao Yonghui ， et al . Research progress on the classification and key factors of carnot batteries ［J/OL］. Materials Reports ， 1 - 28 （ 2025-10-20 ）［ 2026-01-04 ］. https：//link.cnki.net/urlid/50.1078.TB.20251019.1651.006 https://link.cnki.net/urlid/50.1078.TB.20251019.1651.006 .

肖振坤，陈珍，杨壮，等 . 基于相变储热的先进高温热泵储能单元的热力学分析［J］. 储能科学与技术， 2024 ， 13 （ 12 ）： 4330 - 4338 .

Xiao Zhenkun ， Chen Zhen ， Yang Zhuang ， et al . Thermodynamic analysis of an advanced high-temperature heat pump energy storage unit based on phase-change heat storage ［J］. Energy Storage Science and Technology ， 2024 ， 13 （ 12 ）： 4330 - 4338 .

Zauner C ， Windholz B ， Lauermann M ， et al . Development of an energy efficient extrusion factory employing a latent heat storage and a high temperature heat pump ［J］. Applied Energy ， 2020 ， 259 ： 114114 .

Kumar Reddy Y S ， Dharmasena P ， Nassif N . A novel R718 two-stage wet-compression industrial heat pump integrated with thermal energy storage for enhancing grid flexibility ［J］. Energy Conversion and Management ， 2026 ， 350 ： 120951 .

Arpagaus C ， Bless F ， Uhlmann M ， et al . High temperature heat pumps： market overview， state of the art， research status， refrigerants， and application potentials ［J］. Energy ， 2018 ， 152 ： 985 - 1010 .

周亮，贾冠伟，郭泽宇，等 . 空压机余热回收利用技术［J］. 液压与气动， 2023 ， 47 （ 1 ）： 22 - 31 .

Zhou Liang ， Jia Guanwei ， Guo Zeyu ， et al . Air compressor waste heat recovery and utilization technology ［J］. Chinese Hydraulics & Pneumatics ， 2023 ， 47 （ 1 ）： 22 - 31 .

贺金，匡胜严，谢垚，等 . 离心式空压机余热制冷/热系统分析［J］. 暖通空调， 2024 ， 54 （ 8 ）： 61 - 66 .

He Jin ， Kuang Shengyan ， Xie Yao ， et al . Analysis of centrifugal air compressor waste heat for cooling and heating systems ［J］. Heating Ventilating & Air Conditioning ， 2024 ， 54 （ 8 ）： 61 - 66 .

Lemmon E W ， Bell I H ， Huber M L ， et al . NIST standard reference database 23： reference fluid thermodynamic and transport properties-REFPROP， Version 10.0， National Institute of Standards and Technology ［J］. Standard Reference Data Program ， Gaithersburg， 2018 ： 45 - 46 .

Abedini H ， Vieren E ， Demeester T ， et al . A comprehensive analysis of binary mixtures as working fluid in high temperature heat pumps ［J］. Energy Conversion and Management ， 2023 ， 277 ： 116652 .

Nallusamy N ， Sampath S ， Velraj R . Experimental investigation on a combined sensible and latent heat storage system integrated with constant/varying （solar） heat sources ［J］. Renewable Energy ， 2007 ， 32 （ 7 ）： 1206 - 1227 .

Schulz M ， Kourkoulas D . Regulation （EU） No 517/2014 of the European Parliament and of the Council of 16 April 2014 on fluorinated greenhouse gases and repealing Regulation （EC） No 842/2006 ［J］. Official Journal of the European Union ， 2014 ， 2014 （ 517 ）： L150 .

NFPA 704-2022 Standard system for the identification of the hazards of materials for emergency response ［S］.

王占博 . 超临界有机朗肯循环非共沸混合工质筛选准则与混合工质有机朗肯循环实验研究［D］. 北京：华北电力大学， 2021 .

Wang Zhanbo . Screening criteria of zeotropic mixtures for the trans-critical organic Rankine cycle and experimental investigation on the organic Rankine cycle with mixture working fluid ［D］. Beijing ： North China Electric Power University ， 2021 .

刘佳昕，陈健勇，陈颖，等 . 采用干工质的补气增焓高温热泵循环热力学分析［J］. 制冷学报， 2024 ， 45 （ 6 ）： 41 - 49 .

Liu Jiaxin ， Chen Jianyong ， Chen Ying ， et al . Thermodynamic analysis of vapor injection heat pump cycle with dry working fluid ［J］. Journal of Refrigeration ， 2024 ， 45 （ 6 ）： 41 - 49 .

Xu Chang ， Ma Hongting ， Yu Xiaohui . Comprehensive performance evaluation method of working fluids for high temperature heat pump based on multi-objective optimization ［J］. Applied Thermal Engineering ， 2024 ， 247 ： 123102 .

折晓会，王星宇，郭晓龙，等 . 超低温-高温跨温区相变材料制备及物性调控综述［J］. 储能科学与技术， 2023 ， 12 （ 12 ）： 3818 - 3835 .

She Xiaohui ， Wang Xingyu ， Guo Xiaolong ， et al . A review on the preparation of ultra-low-temperature， high-temperature， and cross-temperature zone phase change materials and the regulation of physical properties ［J］. Energy Storage Science and Technology ， 2023 ， 12 （ 12 ）： 3818 - 3835 .

李俊杰 . 基于主动配液的非共沸工质蓄热热泵系统研究［D］. 广州：广东工业大学， 2025 .

Li Junjie . Study on thermal energy storage heat pump system with zeotropic mixtures based on vapor-liquid adjustment ［D］. Guangzhou ： Guangdong University of Technology ， 2025 .

He Xibo ， Qiu Jun ， Wang Wei ， et al . A review on numerical simulation， optimization design and applications of packed-bed latent thermal energy storage system with spherical capsules ［J］. Journal of Energy Storage ， 2022 ， 51 ： 104555 .

Views

438

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Experimental Study on Header-Orifice Vapor-Liquid Separation Unit Using Zeotropic Mixture

Development Status of Compressor Technology for Medium and Large Capacity Industrial High-Temperature Heat Pumps

Physical Properties and High-Temperature Heat Pump Application Characteristics of the New Environmentally Friendly Refrigerant HP-1

Thermodynamic Analysis of Vapor Injection Heat Pump Cycle with Dry Working Fluid

Performance Analysis and Experimental Study of Quasi-two-stage Heat Pump Cycle

Related Author

何嘉诚

梁颖宗

罗向龙

陈颖

陈健勇

Liang Yingzong He Jiacheng

Chen Guanghao He Yunyun Chen Jianyong Chen Ying Luo Xianglong

Xing Ziwen

Related Institution

Guangdong University of Technology， School of Materials and Energy

Suzhou Academy, Xi'an Jiaotong University

School of Energy and Power Engineering, Xi'an Jiaotong University

Institute of Refrigeration and Cryogenics, Shanghai Jiao Tong University

State Key Laboratory of Fluorinated Greenhouse Gases Replacement and Control Treatment, Zhejiang Research Institute of Chemical Industry Co.，Ltd.

Address：10/F, Yindu Mansion, 67 Fucheng Road, Haidian Dist, Beijing, China Postal code：100142
Tel：010-68711412 Email：editor@car.org.cn
Technical support is provided by Beijing Founder electronics co., LTD 京ICP备09064830号-19 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰

AI伴读