Solar Thermal-Driven Cold Energy Storage Based on a Novel Graphene-Based Composite Sorbent

Wang Kedi; Fu Shikun; Gao Peng; Wu Weidong; Wang Liwei

doi:10.12465/issn.0253-4339.20250726001

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Solar Thermal-Driven Cold Energy Storage Based on a Novel Graphene-Based Composite Sorbent

更新时间：2026-10-13

- Solar Thermal-Driven Cold Energy Storage Based on a Novel Graphene-Based Composite Sorbent
- Journal of Refrigeration Vol. 47, Issue 5, Pages: 52-59(2026)
- 作者机构：
  
  1.上海理工大学能源与动力工程学院上海 200093
  2. 上海交通大学制冷与低温工程研究所上海 200240
- 作者简介：
  
  Peng Gao， male， associate professor， School of Energy and Power Engineering， University of Shanghai for Science and Technology， 86-13761241490. E-mail：p.gao@usst.edu.cn. Research fields： chemisorption energy storage， solar refrigeration.
- 基金信息：
  
  the National Natural Science Foundation of China(52236004;52206017)
- DOI：10.12465/issn.0253-4339.20250726001
  CLC： TK511;TB61;TB64
- Received：26 July 2025，
  
  Revised：2025-09-28，
  
  Accepted：28 September 2025，
  
  Published：16 October 2026
- 稿件说明：
移动端阅览
王科迪,符世鲲,高鹏等.基于新型石墨烯基复合吸附剂的太阳能热驱动蓄冷研究[J].制冷学报,2026,47(05):52-59.

Wang Kedi,Fu Shikun,Gao Peng,et al.Solar Thermal-Driven Cold Energy Storage Based on a Novel Graphene-Based Composite Sorbent[J].Journal of Refrigeration,2026,47(05):52-59.
王科迪,符世鲲,高鹏等.基于新型石墨烯基复合吸附剂的太阳能热驱动蓄冷研究[J].制冷学报,2026,47(05):52-59. DOI： 10.12465/issn.0253-4339.20250726001.

Wang Kedi,Fu Shikun,Gao Peng,et al.Solar Thermal-Driven Cold Energy Storage Based on a Novel Graphene-Based Composite Sorbent[J].Journal of Refrigeration,2026,47(05):52-59. DOI： 10.12465/issn.0253-4339.20250726001.

摘要

针对传统化学吸附剂普遍存在的结构松散、缺乏有效传热传质通道和循环稳定性差等问题，本文提出并制备了一种新型石墨烯基复合吸附剂，该吸附剂通过将氯化锶（SrCl

）嵌入三维互联的石墨烯网络中，构建了连续高效的热传导和传质通道，同时显著增强了吸附剂的循环稳定性与热质传输性能。结果表明：该复合材料在-10 ℃蒸发温度下的氨吸附容量高达0.577 g/g，为理论值的84.1%，单位质量蓄冷能力达到639.89 kJ/kg，是冰蓄冷的1.9倍。在90 ℃驱动热源温度的解吸工况下，氨解吸量达0.572 g/g。在模拟非聚光太阳能集热器热水驱动的定压解吸实验中，系统可在连续4 h稳定日照条件下完成90%以上的蓄冷过程。该新型石墨烯基复合吸附剂在储能密度及循环稳定性方面均展现出优异性能，为太阳能吸附式蓄冷

系统的工程化提供坚实技术支撑。

Abstract

To address the common problems associated with traditional chemisorption sorbents， including their loose structure， lack of effective heat and mass transfer pathways， and poor cycling stability， this study developed a novel graphene-based composite sorbent. By embedding strontium chloride （SrCl

） into a three-dimensionally interconnected graphene network， continuous and efficient channels for heat conduction and mass transfer were constructed， significantly enhancing the sorbent's cycling stability and thermophysical transfer performance. The composite sorbent achieved a high ammonia uptake， of 0.577 g/g， at an evaporation temperature of -10 ℃， reaching 84.1% of the theoretical value. The specific cold storage capacity reached 639.89 kJ/kg， which is 1.9 times that of ice storage. Under a desorption condition driven by a 90 ℃ heat source， the ammonia desorption capacity reached 0.572 g/g. In isobaric desorption experiments that simulates hot water supplied by a non-concentrated solar collector， over 90% of the cold storage process was completed within 4 h of stable sunlight. The proposed graphene-based composite sorbent demonstrated excellent performance in terms of both energy storage density and cyclic stability， thus providing solid technical support for engineering applications of solar-driven chemisorption cold storage systems.

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references

Piselli C ， Balocco C ， Forastiere S ， et al . Energy efficiency in the commercial sector. Thermodynamics fundamentals for the energy transition ［J］. Energy Reports ， 2024 ， 11 ： 4601 - 4621 .

International Institute of Refrigeration . China's cold chain growth： increased capacity and sustainable practices in 2024 ［EB/OL］. （ 2025-02-06 ）［ 2025-07-15 ］. https：//iifiir.org/en/news/china-s-cold-chain-growth-increased-capacity-and-sustainable-practices-in-2024 https://iifiir.org/en/news/china-s-cold-chain-growth-increased-capacity-and-sustainable-practices-in-2024 .

赖坤，田健 . 带喷射器的跨临界CO 2 系统在大型冷库中的应用［J］. 制冷学报， 2025 ， 46 （ 2 ）： 162 - 170 .

Lai Kun ， Tian Jian . Application of transcritical CO 2 system with ejector in large cold store ［J］. Journal of Refrigeration ， 2025 ， 46 （ 2 ）： 162 - 170 .

王雅博，尹玉成，刘兴华，等 . 冷库空气幕气流组织优化及冷风渗透实验［J］. 制冷学报， 2023 ， 44 （ 2 ）： 137 - 143 .

Wang Yabo ， Yin Yucheng ， Liu Xinghua ， et al . Optimization of airflow organization and cold air infiltration experiment of air curtain in cold storage ［J］. Journal of Refrigeration ， 2023 ， 44 （ 2 ）： 137 - 143 .

Li Sihui ， Peng Jinqing ， Li Houpei ， et al . Zero energy potential of PV direct-driven air conditioners coupled with phase change materials and load flexibility ［J］. Renewable Energy ， 2022 ， 200 ： 419 - 432 .

Sarmouk M D ， Smaili A ， Fellouah H ， et al . Experimental and numerical investigations of a solar space heating system based on design of experiments method ［J］. Solar Energy ， 2021 ， 216 ： 396 - 410 .

Ding Zhixiong ， Wu Wei ， Chen Youming ， et al . Dynamic characteristics and performance improvement of a high-efficiency double-effect thermal battery for cooling and heating ［J］. Applied Energy ， 2020 ， 264 ： 114768 .

Zhou Yuekuan ， Zheng Siqian ， Zhang Guoqiang . A review on cooling performance enhancement for phase change materials integrated systems—flexible design and smart control with machine learning applications ［J］. Building and Environment ， 2020 ， 174 ： 106786 .

Gao Yuhe ， Ji Jie ， Han Kedong ， et al . Comparative analysis on performance of PV direct-driven refrigeration system under two control methods ［J］. International Journal of Refrigeration ， 2021 ， 127 ： 21 - 33 .

Alobaid M ， Hughes B ， Calautit J K ， et al . A review of solar driven absorption cooling with photovoltaic thermal systems ［J］. Renewable and Sustainable Energy Reviews ， 2017 ， 76 ： 728 - 742 .

Wang J ， Hu E ， Blazewicz A ， et al . Simulation of accumulated performance of a solar thermal powered adsorption refrigeration system with daily climate conditions ［J］. Energy ， 2018 ， 165 ： 487 - 498 .

胡皓，高鹏，金胜祥，等 . 压缩强化解吸的新型吸附制冷系统性能研究［J］. 制冷学报， 2022 ， 43 （ 6 ）： 130 - 137 .

Hu Hao ， Gao Peng ， Jin Shengxiang ， et al . Investigation of a novel compression-assisted decomposition chemisorptiona refrigeration system ［J］. Journal of Refrigeration ， 2022 ， 43 （ 6 ）： 130 - 137 .

Cao Zhejian ， Akhtar F . Porous strontium chloride scaffolded by graphene networks as ammonia carriers ［J］. Advanced Functional Materials ， 2021 ， 31 （ 30 ）： 2008505 .

Wu S ， Li T X ， Wang R Z . Experimental identification and thermodynamic analysis of ammonia sorption equilibrium characteristics on halide salts ［J］. Energy ， 2018 ， 161 ： 955 - 962 .

Sharma R ， Kumar E A . Ammoniated salt-based gas-solid sorption devices ［J］. Thermal Science and Engineering Progress ， 2020 ， 19 ： 100652 .

Li Sitong ， Li Zhuqing ， Chen Yu ， et al . A SrBr 2 /SrCl 2 -expanded graphite comp osite material for low temperature thermochemical energy storage ［J］. Journal of Energy Storage ， 2024 ， 104 ： 114540 .

N'tsoukpoe K E ， Rammelberg H U ， Lele A F ， et al . A review on the use of calcium chloride in applied thermal engineering ［J］. Applied Thermal Engineering ， 2015 ， 75 ： 513 - 531 .

刘金亚，朱芳啟，江龙，等 . 以膨胀硫化石墨为基质的氯化钙/氯化钡-氨两级复合吸附式制冷循环实验研究［J］. 制冷学报， 2017 ， 38 （ 2 ）： 51 - 56 .

Liu Jinya ， Zhu Fangqi ， Jiang Long ， et al . Experimental study on the CaCl 2 /BaCl 2 -NH 3 two-stage chemisorption refrigeration cycle based on the matrix of expanded natural graphite treated with sulfuric acid ［J］. Journal of Refrigeration ， 2017 ， 38 （ 2 ）： 51 - 56 .

Jiang L ， Wang L W ， Wang R Z . Investigation on thermal conductive consolidated composite CaCl 2 for adsorption refrigeration ［J］. International Journal of Thermal Sciences ， 2014 ， 81 ： 68 - 75 .

Zhang Lei ， Wang Ruzhu ， Xia Zhongzhi . Consolidated composite sorbents with expanded natural graphite for adsorption refrigeration： a review ［J］. Renewable and Sustainable Energy Reviews ， 2016 ， 65 ： 529 - 543 .

Satheeshkumar P ， Immanuel Selwynraj A . Experimental studies of activated carbon/graphite composite adsorbent for improved performance of packed and coated bed adsorption cooling system ［J］. Results in Engineering ， 2024 ， 23 ： 102800 .

公绪金，王君竹，董玉奇 . CaCl 2 /石墨烯复配对活性炭-甲醇工质对吸附解吸特性的影响［J］. 制冷学报， 2023 ， 44 （ 1 ）： 104 - 113 .

Gong Xujin ， Wang Junzhu ， Dong Yuqi . Effects of CaCl 2 impregnation and graphene blending on adsorption refrigeration with activated carbon-methanol working pair ［J］. Journal of Refrigeration ， 2023 ， 44 （ 1 ）： 104 - 113 .

Xia Li ， Zhang Yue ， Zhao Jing ， et al . Multifactor performance evaluation of an energy-saving methanol production process coupled refrigeration-power system driven by waste heat ［J］. Fuel ， 2024 ， 375 ： 132581 .

Chao Jingwei ， Xu Jiaxing ， Yan Taisen ， et al . Enhanced thermal conductivity and adsorption rate of zeolite 13X adsorbent by compression-induced molding method for sorption thermal battery ［J］. Energy ， 2022 ， 240 ： 122797 .

Zhang Wenjing ， Fu Shikun ， Gao Peng ， et al . Solar photovoltaic refrigeration system coupled with a flexible， cost-effective and high-energy-density chemisorption cold energy storage module ［J］. Energy ， 2024 ， 304 ： 132163 .

Luo H L ， Dai Y J ， Wang R Z ， et al . Experimental investigation of a solar adsorption chiller used for grain depot cooling ［J］ . Applied Thermal Engineering ， 2006 ， 26 （ 11/12 ）： 1218 - 1225 .

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