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压缩式热泵耦合相变材料储热的研究进展
杨耿1, 肖鑫1, 王云峰2,2
0
(1.东华大学环境学院;2.云南省农村能源工程重点实验室)
摘要:
近年来,潜热储能热管理在热泵中的应用受到广泛关注。将相变蓄热技术与热泵结合可提升热泵性能以及对可再生能源的利用率,但仍需进一步降本增效。为此,综述了近年来压缩式热泵与相变材料耦合储热的研究进展,分类概述了不同应用场景下相变材料相关热物性的适用条件及其表征方法。概括了热泵储能系统性能的优化途径,包括相变材料选取原则与改良方法、储热器的优化设置思路和相关原理、系统的动态优化控制策略等。梯级相变蓄热型热泵在提升供给侧舒适性和提高可再生能源利用率等方面的突出表现,表明了梯级蓄热应用于热泵储能系统中的广阔前景,提出非共晶混合相变材料作为梯级蓄热的备选材料的观点。指出需要总结和开发出储能相变材料热物性可调控的新方法,使得相变材料的选取和改良技术与梯级蓄热装置的热力学理论优化研究相适应,进一步提升相变蓄热型热泵的供热脱碳能力。
关键词:  热泵储能  潜热储能  相变材料  梯级蓄热
DOI:
投稿时间:2023-12-06修订日期:2024-01-05
基金项目:上海市浦江人才计划(No. 20PJ1400200);云南省农村能源工程重点实验室开放基金重点项目(No. 2022KF001);中央高校基本科研业务费专项基金(No. 2232021D-11);上海市引进海外高层次人才计划;东华大学高层次人才专项基金。
Research Progress of Compression Heat Pump Coupled with Phase Change Materials for Heat Storage
Abstract:
In recent years, the research of regenerative heat pump has been widely concerned. The combination of phase change heat storage technology and heat pump can improve the performance of heat pump and the utilization rate of renewable energy, but it still needs further cost reduction and efficiency increase. Therefore, the present study reviews the progress of solid-liquid phase change regenerative heat pumps, and summarizes the applicable conditions and characterization methods of phase change materials applied to heat pumps. The optimization approaches of the performance of the regenerative heat pump system are summarized, including the selection and improvement of phase change materials, the optimal setting of heat exchanger, and the dynamic optimization control strategy of the system. The outstanding performance of regenerative heat pump with cascade heat storage in improving the supply-side comfort and improving the utilization rate of renewable energy indicates the broad prospect of cascade heat storage applied to heat pump energy storage system, and the non-eutectic mixed phase change materials are proposed as alternative materials for cascade heat storage. It is pointed out that it is necessary to summarize and develop new methods to adjust the thermophysical properties of phase change materials for energy storage, so that make the selection and improvement of phase change materials adapt to the optimization research of thermodynamic theory of cascade heat storage device, and further improve the heating decarbonization ability of latent heat storage heat pump.
Key words:  heat pump energy storage  latent heat storage  phase change material  cascade heat storage

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