Wang Zanshe, Yang Lisheng, Hu Xianwei, et al. Improvement and Experimental Study of the T-history Method[J]. Journal of refrigeration, 2017, 38(6).
DOI:
Wang Zanshe, Yang Lisheng, Hu Xianwei, et al. Improvement and Experimental Study of the T-history Method[J]. Journal of refrigeration, 2017, 38(6). DOI: 10.3969/j.issn.0253-4339.2017.06.034.
Improvement and Experimental Study of the T-history Method
Phase-change heat-storage material (PCM) is widely used in many fields
and its thermophysical properties are the key factor for its application. In this study
an improvement of the T-history method is presented
based on the basic principle of the T-history curve method
the theoretical step curve of the PCM and the actual step-curve measurement process. Firstly
according to crystalline-melting thermodynamic conditions
a certain degree of supercooling is necessary for crystal crystallization; therefore
there is sensible heat between the phase-change-start phase and the phase-change-end phase. Then
the energy-balance equation was improved by considering the sensible heat effect on the energy-balance equation in the phase-change stage
and the temperature-difference effect on the energy-balance equation in the cooling process of the phase-transition phase. Secondly
the phase-change material was placed in a constant-temperature water source at 70 ℃ until it melted. Then
it was placed in a constant-temperature box at 10 ℃. The step curve was obtained with a two-second interval measurement. Finally
the experimental results for three phase-change materials
sodium dodecahydrate disodium phosphate
lauric acid
and stearic acid
were calculated according to the improved equations to verify the improvement of the T-history method. The results show that the calculated value of the latent heat is closer to that of the differential-scanning calorimetry process
and the error is less than 10%. Therefore
the improvement of the T-history method has a certain practical significance for the development and testing of phase-change thermal energy storage material.