Thermophysical Properties of Cool Storage of Paraffin-based Composite Phase Change Materials Filled with Carbon Nanotubes

doi:10.3969/j.issn.0253-4339.2014.05.020

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Thermophysical Properties of Cool Storage of Paraffin-based Composite Phase Change Materials Filled with Carbon Nanotubes

更新时间：2025-09-03

- Thermophysical Properties of Cool Storage of Paraffin-based Composite Phase Change Materials Filled with Carbon Nanotubes
- Journal of Refrigeration Vol. 35, Issue 5, Pages: 110-113(2014)
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- DOI：10.3969/j.issn.0253-4339.2014.05.020
  CLC： TK124(热能、热力工程);TB383(工程材料学)
- Published：2014
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Thermophysical Properties of Cool Storage of Paraffin-based Composite Phase Change Materials Filled with Carbon Nanotubes[J]. Journal of Refrigeration, 2014, 35(5): 110-113.
DOI：

Thermophysical Properties of Cool Storage of Paraffin-based Composite Phase Change Materials Filled with Carbon Nanotubes[J]. Journal of Refrigeration, 2014, 35(5): 110-113. DOI： 10.3969/j.issn.0253-4339.2014.05.020.

摘要

针对石蜡导热系数低，传热性能差的缺点，采用向其中添加碳纳米管来改善其导热性能。实验制备了碳纳米管质量分数为1％、2％和5％的石蜡基复合相变材料，通过差示扫描量热仪和热传导系数仪研究了复合材料的相变性能，导热性能和稳定性。实验结果表明，随着碳纳米管质量分数的增加，复合材料的导热系数逐渐增大，相变焓有所减小。质量分数为5％的石蜡基碳纳米管复合材料相变温度为4~8℃，相变焓为137?6~142?7 kJ/kg，比纯石蜡下降了约18％，液态导热系数为0?28 W/( m?K)，比纯石蜡提高了40％，稳定性较好，可作为蓄冷材料广泛应用于蓄冷系统。

Abstract

To address thermal conductivity of paraffin wax (PW)

carbon nanotubes (CNTs) were mixed with PW to form PW-CNTs composites.PW-CNTs composites has been prepared with various mass fractions (1% 、2%、5%) of carbon nanotubes.The thermal properties including phase transition temperature

latent heat of phase change

thermal conductivity and thermal stability during the phase change process are investigated.The phase change property was characterized using differential scanning calorimeter(DSC) and the thermal conductivity was measured by using transient hot wire method.The results show that with the increasing of mass fraction of CNTs

thermal conductivity become larger

and the latent heat decrease gradually.Phase transition temperature of PW-5CNTs is 4-8 ℃

latent heat of phase change is 137.6-142.7 kJ/kg

thermal conductivity is 0.28 W/(m?K)(liquid)

and PW-5CNTs have good enough stability to be widely used as cool storage materials.

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references

马炳倩,李建强,彭志坚,等.石蜡基复合相变储热材料的导热性能[J].储能科学与技术.2012,(2).

Jifen Wang,Zhong Xin,Huaqing Xie.Increasing the thermal conductivity of palmitic acid by the addition of carbon nanotubes[J].Carbon: An International Journal Sponsored by the American Carbon Society.2010,48(14).

Ho-Ki Lyeo,Stephen G. Bishop,Min-Ho Kwon,等.Thermal conductivity of phase-change material Ge_2Sb_2Te_5[J].Applied Physics Letters.2006,89(15).

P, Kim,L, Shi,A, Majumdar,等.Thermal transport measurements of individual multiwalled nanotubes.[J].Physical review letters.2001,87(21).215502.

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Related Institution

[1]南京大学物理系制冷教研室,南京210093 [2]南京大学材料科学与工程系

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