Evaporation of functional nanoparticle-containing droplets on solid surfaces is a key process in several fields
such as air conditioning
refrigeration
and electronics cooling. In this paper
we experimentally investigate nanofluid droplets' evaporation and particle deposition process on solid surfaces
photograph the deposition patterns
and perform microscopic characterization. The results show that the droplets always evaporate in the mode of constant contact radius
the changes in substrate temperature and droplet volume have little influence on the evaporation mode and morphology of the droplets
and the contact angle changes linearly with time. The surfactant can significantly regulate the kinetic behavior of droplet spreading
and the addition of only 0.25 wt % of surfactant sodium dodecyl sulfate (SDS) increases the droplet spreading radius from 0.71 mm to 1.12 mm
the initial contact angle decreases from 83° to 54°
and the area of spreading increases by 89%. Substrate temperature and droplet volume significantly affect the deposition pattern after droplet evaporation. The higher the substrate temperature
the larger the droplet volume
and the more obvious coffee ring pattern is formed after evaporation. SDS significantly increases the coffee ring width
which reaches 230 μm when the concentration of SDS reaches 1%
and the particles have been widely distributed throughout the entire evaporation area
suggesting that the coffee ring effect has been effectively suppressed. By introducing the Ma number
the influence of the Marangoni effect guided by temperature
volume
and concentration changes on the internal flow of droplets and the mechanism of coffee ring formation is explained.
关键词
纳米流体液滴蒸发颗粒自组装咖啡环
Keywords
nanofluidsdroplet evaporationParticle self-assemblyCoffee ring